If you have a free character slot you can make a pvp only char, make a sorta copy of your most liked pve char and make modifications for pvp. To know what needs to be modified you can try the pvp section of this forum, or gain experience in the random arena.
If you don't have a guild it would also be a good idea to start looking for a pvp guild, so you can get into the pvp with helpfull people.
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